Homogeneous Catalysis

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Opis: Homogeneous Catalysis - Doble Mukesh, Sumit Bhaduri

The only up-to-date, concise textbook available for a short course in organometallic chemistry and homogeneous catalysis, Homogeneous Catalysis clearly explains the basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues. Providing a balanced treatment of the recent breakthroughs and developments while also detailing earlier discoveries and the fundamentals of homogeneous catalysis, the text provides problems and answers, along with real-life case studies, extensive references to cutting-edge research with application potential and leading patents, and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues.1. Chemical Industry and Homogeneous Catalysis 1.1 Feed Stocks, Fuels and Catalysts 1.2 Crude Oil to Gasoline and Basic Building Blocks by Heterogeneous catalysts 1.3 Basic Building Blocks to Downstream Products by Homogeneous Catalysis 1.4 Comparison among Different Types of Catalysis 1.5 Catalyst Recovery 1.6 Environmental Issues Problems Bibliography 2. Basic Chemical Concepts 2.1 Ligands 2.2 Metals 2.3 Important Reaction Types Problems Bibliography 3. Methods of Investigation 3.1 Catalytic cycle and intermediates 3.2 Spectroscopic Studies 3.3 Kinetic Studies 3.4 Model Compounds 3.5 Computational Techniques (Theoretical Calculation) 3.6 Asymmetric Catalysis Problems Bibliography 4. Carbonylation and Related Reactions 4.1 Introduction 4.2 Carbonylation and Manufacture of Acetic Acid 4.3 Carbonylation of Other Alcohols 4.4 Carbonylation of Methyl Acetate 4.5 Carbonylation of Alkynes 4.6 Other carbonylation and hydrocarboxylation reactions 4.7 C 1 -Chemistry 4.8 Engineering Aspects Problems Bibliography 5. Hydrogenation and Other Hydrogen Based Catalytic Reactions 5.1 Hydrogenation 5.2 Hydroformylation 5.3 Other Hydroformylation reactions 5.4 Asymmetric Hydroformylation 5.5 Hydrosilylation 5.6 Hydrocyanation 5.7 Hydroamination Problems Bibliography 6. Polymerization and Selective Oligomerization of Alkenes 6.1 Introduction 6.2 Early Catalysts for Polyethylene and Polypropylene 6.3 Modern Ziegler-Natta Catalyst 6.4 Mechanistic Studies 6.5 Single Site Catalysts 6.6 Ethylene Polymerization with Polar comonomers 6.7 Polymers of Other Alkenes 6.8 Oligomerization of Ethylene 6.9 Engineering Aspects Problems Bibliography 7. Selective C-C Bond Forming Reactions With Alkenes 7.1 Introduction 7.2 Di-, Tri-, Tetramerization and Codimerization reactions 7.3 Metathesis Reactions 7.4 Pd-Catalyzed Cross Coupling Reactions 7.5 Metal catalyzed Cyclopropanation and Cycloaddition Problems Bibliography 8. Oxidation 8.1 Introduction 8.2 Wacker Oxidation 8.3 Metal-Catalyzed Liquid-Phase Autoxidation 8.4 Polymers from Autoxidation Products 8.5 Selective Oxidations 8.6 Engineering and Safety Considerations Problems Bibliography


Szczegóły: Homogeneous Catalysis - Doble Mukesh, Sumit Bhaduri

Tytuł: Homogeneous Catalysis
Autor: Doble Mukesh, Sumit Bhaduri
Producent: John Wiley
ISBN: 9781118139257
Rok produkcji: 2014
Ilość stron: 288
Oprawa: Twarda


Recenzje: Homogeneous Catalysis - Doble Mukesh, Sumit Bhaduri

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Homogeneous Catalysis

,

The only up-to-date, concise textbook available for a short course in organometallic chemistry and homogeneous catalysis, Homogeneous Catalysis clearly explains the basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues. Providing a balanced treatment of the recent breakthroughs and developments while also detailing earlier discoveries and the fundamentals of homogeneous catalysis, the text provides problems and answers, along with real-life case studies, extensive references to cutting-edge research with application potential and leading patents, and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues.1. Chemical Industry and Homogeneous Catalysis 1.1 Feed Stocks, Fuels and Catalysts 1.2 Crude Oil to Gasoline and Basic Building Blocks by Heterogeneous catalysts 1.3 Basic Building Blocks to Downstream Products by Homogeneous Catalysis 1.4 Comparison among Different Types of Catalysis 1.5 Catalyst Recovery 1.6 Environmental Issues Problems Bibliography 2. Basic Chemical Concepts 2.1 Ligands 2.2 Metals 2.3 Important Reaction Types Problems Bibliography 3. Methods of Investigation 3.1 Catalytic cycle and intermediates 3.2 Spectroscopic Studies 3.3 Kinetic Studies 3.4 Model Compounds 3.5 Computational Techniques (Theoretical Calculation) 3.6 Asymmetric Catalysis Problems Bibliography 4. Carbonylation and Related Reactions 4.1 Introduction 4.2 Carbonylation and Manufacture of Acetic Acid 4.3 Carbonylation of Other Alcohols 4.4 Carbonylation of Methyl Acetate 4.5 Carbonylation of Alkynes 4.6 Other carbonylation and hydrocarboxylation reactions 4.7 C 1 -Chemistry 4.8 Engineering Aspects Problems Bibliography 5. Hydrogenation and Other Hydrogen Based Catalytic Reactions 5.1 Hydrogenation 5.2 Hydroformylation 5.3 Other Hydroformylation reactions 5.4 Asymmetric Hydroformylation 5.5 Hydrosilylation 5.6 Hydrocyanation 5.7 Hydroamination Problems Bibliography 6. Polymerization and Selective Oligomerization of Alkenes 6.1 Introduction 6.2 Early Catalysts for Polyethylene and Polypropylene 6.3 Modern Ziegler-Natta Catalyst 6.4 Mechanistic Studies 6.5 Single Site Catalysts 6.6 Ethylene Polymerization with Polar comonomers 6.7 Polymers of Other Alkenes 6.8 Oligomerization of Ethylene 6.9 Engineering Aspects Problems Bibliography 7. Selective C-C Bond Forming Reactions With Alkenes 7.1 Introduction 7.2 Di-, Tri-, Tetramerization and Codimerization reactions 7.3 Metathesis Reactions 7.4 Pd-Catalyzed Cross Coupling Reactions 7.5 Metal catalyzed Cyclopropanation and Cycloaddition Problems Bibliography 8. Oxidation 8.1 Introduction 8.2 Wacker Oxidation 8.3 Metal-Catalyzed Liquid-Phase Autoxidation 8.4 Polymers from Autoxidation Products 8.5 Selective Oxidations 8.6 Engineering and Safety Considerations Problems Bibliography

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