Opis: Bioinspired Catalysis

This book provides an overview of bioinspired metal-sulfur catalysis by covering structures, activities and model complexes of enzymes exhibiting metal sulphur moieties in their active center.PART I: PRIMORDIAL METAL-SULFUR MEDIATED REACTIONS§From Chemical Invariance to Genetic Variability§Fe-S Clusters: Biogenesis and Redox, Catalytic and Regulatory Properties§PART II: MODEL COMPLEXES OF THE ACTIVE SITE OF HYDROGENASES - PROTON AND DIHYDROGEN ACTIVATION§[NiFe] Hydrogenases§[Fe-Fe]Hydrogenases Models: An Overview§The Third Hydrogenase§DFT Investigation of Models Related to the Active Site of Hydrogenases§Mechanistic Aspects of Biological Hydrogen Evolution and Uptake§PART III: NITROGEN FIXATION§Structures and Functions of the Active Site of Nitrogenases§Model Complexes of the Active Site of Nitrogenases: Recent Advances§A Unified Chemical Mechanism for Hydrogenation Reactions Catalysed by Nitrogenase§Binding Substrates to Synthetic Fe-S-Based Clusters and the Possible Relevance to Nitrogenases§PART IV: MISCELLANEOUS: RCN ACTIVATION, DMSO REDUCTION§Sulfur-Oxygenation and Functional Models of Nitrile Hydratase§Molybdenum and Tungsten Oxidoreductase Models§PART V: APPLICATIVE PERSPECITVES§Electrode Materials and Artificial Photosynthetic Systems

Szczegóły: Bioinspired Catalysis

Tytuł: Bioinspired Catalysis
Producent: VCH
ISBN: 9783527333080
Rok produkcji: 2014
Ilość stron: 440
Oprawa: Twarda

Recenzje: Bioinspired Catalysis