Pincer and Pincer-Type Complexes

  • Producent: VCH
  • Oprawa: Twarda
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Opis: Pincer and Pincer-Type Complexes

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights.§The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis.§A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.Preface§§CATALYSIS BY PINCER COMPLEXES: SYNTHESIS OF ESTERS, AMIDES, AND PEPTIDES§Introduction and Background§Bond Activatio by Metal-Ligand Cooperation§Synthesis of Esters§Synthesis of Amides§Synthesis of Peptides from Beta-Amino Alcohols§Concluding Remarks§§THE ROLE OF REDOX PROCESSES IN REACTIONS CATALYZED BY NICKEL AND PALLADIUM COMPLEXES WITH ANIONIC PINCER LIGANDS§Introduction§Pincer Complexes of Ni, Pd, and Pt in Oxidation States Different from II§Catalytic Reactions Involving Redox Processes in the Pincer-Metal Framework§Concluding Remarks§§APPENDED FUNCTIONALITY IN PINCER LIGANDS§Introduction§Appended Functionality Coplanar with the Pincer Chelate§Appended Functionality Not Coplanar to the Pincer Chelate§Future Outlook and Summary§§C-C, C-O, AND C-B BOND FORMATION BY PINCER COMPLEXES INCLUDING ASYMMETRIC CATALYSIS§Introduction - Pros and Cons of Using Pincer Complexes in Catalysis§Reaction of Imines and Isocyanoacetates§C-H Functionalization of Organonitriles§Reactions Involving Hypervalent Iodines§Summary and Outlook§§NICKEL-CATALYZED CROSS-COUPLING REACTIONS§Introduction§Carbon-Carbon Bond-Forming Reactions§Carbon-Heteroatom Bond-Forming Reactions§Summary and Outlook§§PSiP TRANSITION-METAL PINCER COMPLEXES: SYNTHESIS, BOND ACTIVATION, AND CATALYSIS§Introduction§PSiP Ligand Syntheses§Group 8 Metal PSiP Chemistry§Group 9 Metal PSiP Chemistry§Group 10 Metal PSiP Chemistry§Group 11 Metal PSiP Chemistry§Alternative Silyl Pincers§Summary§§ELECTRONIC STRUCTURES OF REDUCED MANGANESE, IRON, AND COBALT COMPLEXES BEARING REDOX-ACTIVE BIS(IMINO)PYRIDINE PINCER LIGANDS§Introduction§Reduced Manganese, Iron, and Cobalt Complexes with Redox-Active Bis(imino)pyridines§Conclusions and Outlook§§PINCER COMPLEXES WITH SATURATED FRAMEWORKS: SYNTHESIS AND APPLICATIONS§Introduction§Synthesis of the Ligands§Synthesis and Coordination Behavior of Carbometallated PC(sp3)P Complexes§Reactivity and Catalytic Applications of PC(sp3) Complexes§§HEAVIER GROUP 14 ELEMENTS-BASED PINCER COMPLEXES IN CATALYTIC SYNTHETIC TRANSFORMATIONS OF UNSATURATED HYDROCARBONS§Introduction§Synthesis of Palladium Complexes Bearing PXP-Pincer Ligands (X=Si, Ge, Sn)§Hydrocarboxylation§Reductive Aldol Type Reaction§Dehydrogenative Borylation§Synthesis and Reaction of n2-(Si-H)Pd(0) Complex as an Equivalent to PSiP-Palladium Hydride Complexes§Conclusions§§EXPERIMENTAL AND THEORETICAL ASPECTS OF PALLADIUM PINCER-CATALYZED C-C CROSS-COUPLING REACTIONS§C-C Cross-Coupling Reactions - An Indispensable Tool for the Synthesis of Complex Organic Molecules§Palladium Pincer Complexes as C-C Cross-Coupling Catalysts§The Role of Palladium Pincer Complexes in Heck Reactions§Computational Investigations on the Thermal Feasibility of PdII/PdIV Cycles of Palladium Pincer-Catalyzed Heck Reactions§Theoretical Investigations on a Pincer-Catalyzed Negishi Cross-Coupling Reaction§Concluding Remarks§§REACTIONS OF SQUARE-PLANAR d8 PINCER COMPLEXES WITH OXYGEN AN HYDROGEN§Introduction§Insertion of Molecular Oxygen into Late-Transition Metal Hydride Bonds§Hydrogenolysis of Late-Transition Metal Hydroxide and Alkoxide Complexes§Summary§§Index


Szczegóły: Pincer and Pincer-Type Complexes

Tytuł: Pincer and Pincer-Type Complexes
Producent: VCH
ISBN: 9783527334421
Rok produkcji: 2014
Ilość stron: 320
Oprawa: Twarda
Waga: 0.84 kg


Recenzje: Pincer and Pincer-Type Complexes

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Pincer and Pincer-Type Complexes

  • Producent: VCH
  • Oprawa: Twarda

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights.§The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis.§A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.Preface§§CATALYSIS BY PINCER COMPLEXES: SYNTHESIS OF ESTERS, AMIDES, AND PEPTIDES§Introduction and Background§Bond Activatio by Metal-Ligand Cooperation§Synthesis of Esters§Synthesis of Amides§Synthesis of Peptides from Beta-Amino Alcohols§Concluding Remarks§§THE ROLE OF REDOX PROCESSES IN REACTIONS CATALYZED BY NICKEL AND PALLADIUM COMPLEXES WITH ANIONIC PINCER LIGANDS§Introduction§Pincer Complexes of Ni, Pd, and Pt in Oxidation States Different from II§Catalytic Reactions Involving Redox Processes in the Pincer-Metal Framework§Concluding Remarks§§APPENDED FUNCTIONALITY IN PINCER LIGANDS§Introduction§Appended Functionality Coplanar with the Pincer Chelate§Appended Functionality Not Coplanar to the Pincer Chelate§Future Outlook and Summary§§C-C, C-O, AND C-B BOND FORMATION BY PINCER COMPLEXES INCLUDING ASYMMETRIC CATALYSIS§Introduction - Pros and Cons of Using Pincer Complexes in Catalysis§Reaction of Imines and Isocyanoacetates§C-H Functionalization of Organonitriles§Reactions Involving Hypervalent Iodines§Summary and Outlook§§NICKEL-CATALYZED CROSS-COUPLING REACTIONS§Introduction§Carbon-Carbon Bond-Forming Reactions§Carbon-Heteroatom Bond-Forming Reactions§Summary and Outlook§§PSiP TRANSITION-METAL PINCER COMPLEXES: SYNTHESIS, BOND ACTIVATION, AND CATALYSIS§Introduction§PSiP Ligand Syntheses§Group 8 Metal PSiP Chemistry§Group 9 Metal PSiP Chemistry§Group 10 Metal PSiP Chemistry§Group 11 Metal PSiP Chemistry§Alternative Silyl Pincers§Summary§§ELECTRONIC STRUCTURES OF REDUCED MANGANESE, IRON, AND COBALT COMPLEXES BEARING REDOX-ACTIVE BIS(IMINO)PYRIDINE PINCER LIGANDS§Introduction§Reduced Manganese, Iron, and Cobalt Complexes with Redox-Active Bis(imino)pyridines§Conclusions and Outlook§§PINCER COMPLEXES WITH SATURATED FRAMEWORKS: SYNTHESIS AND APPLICATIONS§Introduction§Synthesis of the Ligands§Synthesis and Coordination Behavior of Carbometallated PC(sp3)P Complexes§Reactivity and Catalytic Applications of PC(sp3) Complexes§§HEAVIER GROUP 14 ELEMENTS-BASED PINCER COMPLEXES IN CATALYTIC SYNTHETIC TRANSFORMATIONS OF UNSATURATED HYDROCARBONS§Introduction§Synthesis of Palladium Complexes Bearing PXP-Pincer Ligands (X=Si, Ge, Sn)§Hydrocarboxylation§Reductive Aldol Type Reaction§Dehydrogenative Borylation§Synthesis and Reaction of n2-(Si-H)Pd(0) Complex as an Equivalent to PSiP-Palladium Hydride Complexes§Conclusions§§EXPERIMENTAL AND THEORETICAL ASPECTS OF PALLADIUM PINCER-CATALYZED C-C CROSS-COUPLING REACTIONS§C-C Cross-Coupling Reactions - An Indispensable Tool for the Synthesis of Complex Organic Molecules§Palladium Pincer Complexes as C-C Cross-Coupling Catalysts§The Role of Palladium Pincer Complexes in Heck Reactions§Computational Investigations on the Thermal Feasibility of PdII/PdIV Cycles of Palladium Pincer-Catalyzed Heck Reactions§Theoretical Investigations on a Pincer-Catalyzed Negishi Cross-Coupling Reaction§Concluding Remarks§§REACTIONS OF SQUARE-PLANAR d8 PINCER COMPLEXES WITH OXYGEN AN HYDROGEN§Introduction§Insertion of Molecular Oxygen into Late-Transition Metal Hydride Bonds§Hydrogenolysis of Late-Transition Metal Hydroxide and Alkoxide Complexes§Summary§§Index

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Cena 635,00 PLN
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